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The growing severity of global environmental issues in recent years, including air pollution and the depletion of fossil fuels, has made it necessary for internal combustion engines to achieve higher efficiency and lower exhaust emission levels. Calls for reducing atmospheric emissions of carbon dioxide (CO₂) necessitate thoroughgoing measures to lower the levels of CO₂ originating in the combustion process of internal combustion engines and to facilitate operation on diverse energy sources. Homogeneous Charge Compression Ignition (HCCI) combustion has attracted widespread interest because it achieves high efficiency and can reduce particulate matter (PM) and nitrogen oxide (NOx) emissions simultaneously. These characteristics are obtainable because HCCI combustion can take place at ultra-lean conditions exceeding the limits of flame propagation.

The study deals with the light absorption and emission behavior in the preflame reaction interval before hot flame reactions.(1-3) Absorption spectroscopy was used to measure the behavior of HCHO and OH radicals during a progression from normal combustion to knocking operation. Emission spectroscopic measurements were obtained in the same way that radical added HCO. Radical behavior in preflame reactions was thus examined on the basis of simultaneous measurements, which combined each absorption wavelength with three emission wavelength by using a monochromator and a newly developed polychromator.(4-5) When n-heptane (0 RON) and blended fuel (50 RON) were used as test fuel, it was observed that radical behavior differed between normal combustion and knocking operation and a duration of the preflame reaction was shorter during the progression from normal combustion to a condition of knocking.

The uniform lean methanol-air mixture was provided to the diesel engine and was ignited by direct diesel fuel injection. In this study, the internal EGR is added to this ignition method in order to activate the fuel in the mixture and to increase the temperature of the mixture before the ignition. It is confirmed that the lean methanol-air mixture of air-fuel ratio between 130 and 18 could be ignited and burned when the back pressure of 80 [kPa] is added. The ignition and combustion characteristics can be improved by the internal EGR, however the engine performance and NOx emission deteriorated.

In this research, the effect of high-temperature residual gas, resulting from the application of a certain level of EGR, on combustion was investigated using a two-stroke engine and alcohol fuels (ethanol and methanol) and gasoline as the test fuels. Measurements were made of the light emission intensity of the OH radical on the intake and exhaust port sides of the combustion chamber and of the combustion chamber wall temperature (spark plug washer temperature) and the exhaust gas temperature. Data were measured and analyzed in a progression from normal combustion to autoignited combustion to preignition and to knocking operation.

The uniform lean gasoline-air mixture was provided to the diesel engine and was ignited by the direct diesel fuel injection. In this study, the internal EGR is add to this ignition method in order to activate the fuel in the mixture before the ignition. It is confirmed that the lean mixture of air-fuel ratio between 150 and 40 could be ignited and burned by this ignition method when the back pressure of 80 [kPa] is added, and the burning period is shorted by internal EGR. However, as the back pressure increases, NOx concentration is increased by the high temperature residual gas.

The purpose of this study is to realize dual-combustion cycle for gasoline engines. For the purpose, lean combustion and direct fuel injection were applied to small diesel engine. The lean gasoline-air mixture was provided and was ignited by small amount of pilot diesel fuel injection (constant volume combustion). Then, diesel fuel was injected by main injection and was burned with the remained oxygen after the lean combustion (diffusion combustion). The equivalence ratio 0.3, 0.4 and 0.5 of mixture were used to avoid the spontaneous compression auto-ignition. The total equivalence ratio with supplied gasoline and diesel fuel was adjusted to 1.0. The base pilot injection timing was selected as the ignition of pre-mixture took place at T.D.C. and pilot injection timings were changed 2 degree before and behind of base timing. The main fuel injection timings were 50, 75 and 100% of the duration between pilot injection timing and T.D.C.

Homogeneous Charge Compression Ignition (HCCI) has attracted a great deal of interest as a combustion system for internal combustion engines because it achieves high efficiency and clean exhaust emissions. However, HCCI combustion has several issues that remain to be solved. For example, it is difficult to control engine operation because there is no physical means of inducing ignition. Another issue is the rapid rate of heat release because ignition of the mixture occurs simultaneously at multiple places in the cylinder. The results of previous investigations have shown that the use of a blended fuel of DME and propane was observed that the overall combustion process was delayed, with that combustion became steep when injected propane much. This study focused on expanding the region of stable engine operation and improving thermal efficiency by using supercharging and blended fuels. The purpose of using supercharging were in order to moderated combustion.

In this study, a detailed analysis was made of supercharged HCCI combustion using a two-component fuel blend of dimethyl ether (DME), which has attracted interest as a potential alternative fuel, and methane. The quantity of fuel injected and boost pressure were varied to investigate the equivalence ratio and operating region conducive to optimal HCCI combustion. The results revealed that varying the boost pressure according to the engine load and applying a suitable equivalence ratio induced two-stage main combustion over a wide load range, making it possible to avoid excessively rapid combustion.

Knocking is one phenomenon that can be cited as a factor impeding efforts to improve the efficiency of spark-ignition engines. With the aim of understanding knocking better, light emission spectroscopy was applied in this study to examine preflame reactions that can be observed prior to autoignition. Light emission intensity was measured at wavelengths of 306.4 nm (characteristic spectrum of OH), 329.8 nm (HCO), 395.2 nm (HCHO). A four-cycle, air-cooled, single-cylinder gasoline engine with a side valve arrangement was used as the test engine. Light emission behavior was simultaneously observed at two positions (the end zone and the center zone) in the combustion chamber. The test fuel used was n-heptane (0 RON). The test engine was operated at three speed levels (1400, 1800 and 2200 rpm). As a result, preflame reactions were observed. It was also observed that the tendencies seen for the preflame reaction interval varied depending on the engine speed.

In this study, the heated fuels were provided to the diesel engine in order to activate the fuel before the injection. Two test fuels: the normal diesel fuel and cetane, which have different boiling points were used. For both normal diesel fuel and cetane, crank angles at ignition and maximum pressure are delayed and the maximum combustion pressure is decreased as the fuel temperature rises. In cases of large and middle mass flow rate of fuel injection, the brake thermal efficiency and brake mean effective pressure are decreased when the fuel temperature is higher than 570 [K]. However, in the case of small mass flow rate of fuel injection, the brake thermal efficiency is almost independent of fuel temperature. HC and CO concentrations in the exhaust gas emission show constant values regardless of fuel temperature. However, NOx concentration is gradually decreased as the fuel temperature rises.

Attention has recently been focused on homogeneous charge compression ignition combustion (HCCI) as an effective combustion process for resolving the essential nature of combustion. Meanwhile, dimethylether (DME) has attracted interest as a potential alternative fuel for compression ignition engines. Authors measured the combustion process of DME HCCI by using a spectroscopic method. A diesel engine was used as the test engine. The results of these analyses showed that changes in the compression ratio, intake air temperature and equivalence ratio influenced the ignition timing in the HCCI combustion process. This paper discusses these effects in reference to the experimental and calculated results.

The composition ratio of saturated and unsaturated fatty acid methyl esters (FAME) is depended on feedstock. Three FAMEs: soybean (SME), palm (PME) and coconut oil (CME) methyl esters were mixed to make fuels which have different composition ratio. The ignitability of fuel which mainly consisted of unsaturated FAME was inferior. Power was slightly reduced with increasing of mixing ratio of CME; however exhaust gas emissions were improved because CME contained a lot of oxygen atoms. Fuel which was equal mixture SME and CME indicated almost the same ignition characteristic as that of PME because they have same composition ratio.

The flame propagation behavior of hydrogen-air and propane-air mixtures under application of high-voltage non-uniform electric field was explored by using combustion vessel. Both mixtures were ignited by laser-induced breakdown of Nd:YAG laser. In a case of propane-air mixture, top of flame front was drawn to the electrode and bottom of flame front was expanded. In a case of hydrogen-air mixture, the wrinkle caused by the preferential diffusion was enhanced by corona discharge, however the entire flame front was merely moved toward downward by corona wind. Therefore, the non-uniform electric field strongly influences charged particles originated in hydrocarbon of propane-air mixture.

DME is alternate fuel for diesel engines, however DME has defects such as small lower calorific value, inferior lubricity and weak fuel penetration. To compensate disadvantages, In-direct injection 2-stroke diesel engine with low pressure fuel injection system was proposed. The fuel injection timing near TDC gave good performance because the heat loss of low temperature oxidation reaction reduced. The brake torque and brake thermal efficiency of 2-stroke IDI diesel engine were lower than those of 4-stroke engine. However, the exhaust gas emissions were very low level because the intake air leaked through the exhaust port and the exhaust gas was diluted.

A new bio-fuel i.e. the cellulosic liquefaction fuel (CLF) was developed for diesel engines. CLF was made from woods by direct liquefaction process. When neat CLF was supplied to diesel engine, the compression ignition did not occur, so that blend of CLF and diesel fuel was used. The engine could be operated when the mixing ratio of CLF was up to 35 wt%. CO, HC and NOx emissions were almost the same as those of diesel fuel when the mixing ratio of CLF was less than 20 wt% whereas the thermal efficiency slightly decreases with increase in CLF mixing ratio.

The coconut-oil methyl ester is made from coconut oil and methanol, and both cold start performance and ignition characteristics of coconut-oil methyl ester are experimentally investigated by using a diesel engine. In experiments, diesel fuel and coconut-oil methyl ester are used and the blended ratio of coconut-oil methyl ester to diesel fuel is changed. The test is conducted at full load and 3000 rpm. The diesel engine can be run stably with any mixing ratio of coconut-oil methyl ester, however the power is slightly reduced with increasing the mixing ratio of coconut-oil methyl ester. In the cold start condition, when the mixing ratio of coconut-oil methyl ester increases, the combustion chamber wall temperature rises early and the ignition timing is improved. Therefore, the coconut-oil methyl ester has superior compression ignition characteristics and reduces exhaust gas emissions, so that the coconut-oil methyl ester is good alternative fuel for diesel engines.

The use of a higher compression ratio is desirable for improving the thermal efficiency and specific power of spark-ignition engines, but it gives rise to a problem of engine knock. In the present research, an investigation was made of the role of the preflame reaction region of a spark-ignition engine in the occurrence of autoignition. Emission spectroscopy was used to measure the behavior of formaldehyde (HCHO) in a cool flame. In addition, measure the behavior of the faint light attributed to the HCO radical in a blue flame with the concurrent measurement of the OH radical. The emission waveforms measurements obtained for HCHO when n-heptane (ORON) was used as the fuel, It is thought that these tendencies correspond to the passage and degeneracy of a cool flame. Further, the emission waveforms measured for the HCO radical when blended fuels (6ORON, 8ORON) were correspond to that of a blue flame.

There are few investigations to change wood biomasses to the industrially available energy, so that a new conversion technology of biomass to liquid fuel has been established by the direct liquefaction process. However, cellulosic liquefaction fuel (for short CLF) cold not mixed with diesel fuel. In this study, the plastic was mixed with wood to improve the solubility of CLF to diesel fuel. CLF made by the direct co-liquefaction process could be stably and completely mixed with diesel fuel in any mixing ratio and CLF included 2 wt.% of oxygen. The test engine was an air-cooled, four-stroke, single cylinder, direct fuel injection diesel engine. In the engine starting condition test, the ignition timing of 5 wt.% CLF mixed diesel fuel was slightly delayed at immediately after the engine started, however the ignition timing was almost the same as diesel fuel after the engine was warmed-up.

The ignitability and engine performance of FAMEs at the cold condition were experimentally investigated by using two FAMEs, i.e. coconut oil methyl ester (CME) and soybean oil methyl ester (SME). The cold start test and forced over cooling test were conducted. In the forced over cooling test, engine was forced cooled by the injecting water mist to engine cooling fin. In the cold start test, the cylinder pressure of CME rose earliest because CME has a superior ignitability. The crank angle at ignitions of diesel fuel and CME were not so affected by the forced over cooling, however ignition timing of SME was remarkably delayed. In cases of forced over cooling, COV of maximum combustion pressure of CME was lower than that of normal air cooling condition. The forced over cooling has a potential to reduce NOx emission, however HC, CO and smoke concentrations were increased in a high load due to incomplete combustion.

The application of emulsified fuel for diesel engines is expected to reduce NOx and soot simultaneously. The purpose of this study is to clarify the influence of water content in emulsified fuel and fuel injection timing on diesel engine performance. The engine performance of emulsified fuel was compared with the water injection method. In the water injection test, water was injected to intake manifold and diesel fuel was directly injected into combustion chamber. Two emulsified fuels of which mixing ratio of water and emulsifier to diesel fuel were 15 and 30 vol.% were tested. Engine performance and exhaust gas emission of water injection method were almost similar to those of diesel fuel, so that water presented in combustion chamber had almost no influence on engine performance. Therefore, it can be considered that the micro explosion of fuel droplet enhanced the fuel atomization and mixing of fuel and air.